Trisodium Dicarboxymethyl Alaninate (MGDA-Na3)

Trisodium Dicarboxymethyl Alaninate (MGDA-Na3)

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CAS No.: 164462-16-2
Molecular Formula: C7H8NO6Na3
Molecular Weight: 271.1
INCI Name: Trisodium Dicarboxymethyl Alaninate
Chemical Names: Methylglycine N,N-diacetic acid, trisodium salt; Trisodium 2-[bis(carboxylatomethyl)amino]propanoate

Product Description

MGDA-Na3, the abbreviation for Trisodium Methylglycinediacetate, is a low molecular weight chelating agent. Its structure is similar to NTA, but it is non-toxic and readily biodegradable. As a novel, phosphorus-free, green, and degradable chelating agent, MGDA-Na3 serves as an excellent replacement for traditional phosphonates, EDTA, and NTA. It is widely suitable for applications including cleaning agents, detergents, the electroplating & electronics industry, oilfield chemical additives, pulping & papermaking additives, textile auxiliaries, daily chemicals, and personal care products.

Physical and Chemical Properties

 
 
Items MGDA Liquid MGDA Powder MGDA Granule
Appearance Colorless to light yellow transparent liquid White powder White granule
Content /% 40.0 - 42.0 ≥85 ≥78
pH Value (1% solution) 10.0 - 12.0 10.0 - 12.0 10.0 - 12.0
Density (20℃) g/cm³ 1.32 - 1.36 0.5 - 1.5 0.5 - 1.5

Applications in Cleaning and Washing

MGDA-Na3 is biodegradable and enhances the cleaning performance of both household and industrial detergents and cleaners.

  1. Fabric Detergents
    In heavy-duty laundry detergents, liquid laundry detergents, and soap-based detergents, MGDA is particularly effective against stubborn stains such as natural oils, sebum, blood, milk, ink, dust, and protein.
    In formulations containing fatty acids and soap, calcium soap scum can easily form with water hardness ions, depositing on fabric surfaces, causing odor, and reducing wettability. MGDA effectively addresses stains formed by calcium soap and prevents its redeposition.

  2. Phosphorus-Free Dishwasher Detergents
    Following global phosphorus restrictions, various phosphate replacement additives have emerged. Phosphorus-free automatic dishwashing detergent formulations can suffer from reduced filming and stain removal performance. Using MGDA helps bridge this performance gap.
    For stubborn stains like food starch and protein, MGDA has proven highly effective in commercial phosphorus-free formulations, offering efficient rinsing and superior starch stain removal, especially against tea stains.

  3. Cleaning of Inorganic Deposits
    MGDA converts poorly soluble compounds into water-soluble substances, demonstrating excellent dissolving power for inorganic precipitates, with particularly good efficacy on old, dry calcium stains.

    • Cleaning Calcium Carbonate Scale: While acids (e.g., hydrochloric, citric) remove scale by generating CO₂, they are unsuitable for closed or corrosion-sensitive systems. Chelators like MGDA form soluble complexes without these issues and help prevent new scale formation.

    • Cleaning Calcium Phosphate Scale: Insoluble calcium phosphate precipitates, common in dairy processing, are difficult to clean. MGDA's complexing ability for such scale exceeds that of other biodegradable chelating agents.

Packaging and Storage

  • Liquid: Packed in 25kg, 250kg, or 1250kg plastic drums.

  • Powder & Granule: Packed in 25kg craft paper bags.

  • Packaging can be customized according to user requirements.

  • Storage: Store sealed in a dry, ventilated warehouse. Avoid co-storage with acidic or odorous materials. Protect from sun and rain.

Safety Protection

MGDA-Na3 is alkaline. Observe proper industrial hygiene practices during handling. Avoid contact with skin and eyes. In case of contact, rinse thoroughly with plenty of water.

As a professional manufacturer of environmentally friendly biodegradable integrators, Yuanlian can produce MGDA in 40% liquid, 85% powder, and granules.

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